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Collective charge fluctuations in single-electron processes on nanonetworks

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Milovan Šuvakov and Bosiljka Tadić

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Using numerical modeling we study the emergence of structure and structure-related non-linear conduction properties in self-assembled nanoparticle films. In particular, we show how different nanoparticle networks emerge within assembly processes with molecular bio-recognition binding. We then simulate the charge transport under voltage bias via single-electron tunnelings through the junctions between nanoparticles on such networks. We show how the regular nanoparticle array and topologically inhomogeneous nanonetworks affect the charge transport. We find long-range correlations in the time series of charge fluctuation at individual nanoparticles and of flow along the junctions within the network. These correlations explain the occurrence of a large non-linearity in the simulated and experimentally measured current–voltage characteristics and non-Gaussian fluctuations of the current at the electrode.


Keywords

transport properties (theory)

nonlinear dynamics

network dynamics

PACS

87.15.B- Structure of biomolecules

73.23.Hk Coulomb blockade; single-electron tunneling

87.14.G- Nucleic acids

87.15.K- Molecular interactions; membrane-protein interactions

87.15.Ya Fluctuations

87.15.H- Dynamics of biomolecules

MSC

92D20 Protein sequences, DNA sequences

82C70 Transport processes

92C40 Biochemistry, molecular biology

82C80 Numerical methods (Monte Carlo, series resummation, etc.)

Subjects

Surfaces, interfaces and thin films

Biological physics

Dates

Issue 02 (February 2009)

Received 24 October 2008, accepted for publication 14 November 2008

Published 4 February 2009



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