Extreme statistics and volume fluctuations in a confined one-dimensional gas

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Published 21 July 2008 IOP Publishing Ltd
, , Citation Eric Bertin et al J. Stat. Mech. (2008) P07019 DOI 10.1088/1742-5468/2008/07/P07019

1742-5468/2008/07/P07019

Abstract

We consider the statistics of volume fluctuations in a one-dimensional classical gas of non-interacting particles confined by a piston and subjected to an arbitrary external potential. We show that, despite the absence of interactions between particles, volume fluctuations of the gas are non-Gaussian and are described by generalized extreme value distributions. The continuous shape parameter of these distributions is related to the ratio between the force acting on the piston and the force acting on the particles. Gaussian fluctuations are recovered in the strong compression limit, when the effect of the external potential becomes negligible. Consequences for the thermodynamics are also discussed.

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10.1088/1742-5468/2008/07/P07019