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On the law of increase of entropy for non-equilibrium systems

A Pérez-Madrid

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Under the assumption of a smooth full phase-space distribution function we prove that the non-equilibrium entropy S which is considered as a functional of the distribution vector for an N-body system possesses a lower bound and therefore cannot decrease. We also compute the rate of change of S, ∂S/∂t, showing that this is non-negative and having a global minimum at equilibrium. As an application we obtain a generalization of the BGK (Bhatnagar–Gross–Krook) relaxation model.


Keywords

kinetic theory of gases and liquids

rigorous results in statistical mechanics

PACS

05.70.Ln Nonequilibrium and irreversible thermodynamics

05.20.Dd Kinetic theory

MSC

82C35 Irreversible thermodynamics, including Onsager-Machlup theory

82C40 Kinetic theory of gases

Subjects

Statistical physics and nonlinear systems

Dates

Issue 09 (September 2006)

Received 20 June 2006, accepted for publication 12 September 2006

Published 28 September 2006



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