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CHEMISTRY OF SILICATE ATMOSPHERES OF EVAPORATING SUPER-EARTHS

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Laura Schaefer and Bruce Fegley

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We model the formation of silicate atmospheres on hot volatile-free super-Earths. Our calculations assume that all volatile elements such as H, C, N, S, and Cl have been lost from the planet. We find that the atmospheres are composed primarily of Na, O2, O, and SiO gas, in order of decreasing abundance. The atmospheric composition may be altered by fractional vaporization, cloud condensation, photoionization, and reaction with any residual volatile elements remaining in the atmosphere. Cloud condensation reduces the abundance of all elements in the atmosphere except Na and K. We speculate that large Na and K clouds such as those observed around Mercury and Io may surround hot super-Earths. These clouds would occult much larger fractions of the parent star than a closely bound atmosphere, and may be observable through currently available methods.


Keywords

astrochemistry; atmospheric effects; planets and satellites: general


PACS

92.60.Nv Cloud physics; stratus and cumulus clouds

92.60.H- Atmospheric composition, structure, and properties

Subjects

Environmental and Earth science

Dates

Issue 2 (2009 October 1)

Received 2009 June 5, accepted for publication 2009 August 20

Published 2009 September 9



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