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Metallo-supramolecular modules as a paradigm for materials science*

REVIEW ARTICLE

Dirk G Kurth

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TOPICAL REVIEW

Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical, physical and structural properties that make these systems promising candidates for active components in functional materials. A key challenge is to improve and develop methodologies for placing these active modules in suitable device architectures, such as thin films or mesophases. This review highlights recent developments in extended, polymeric metallo-supramolecular systems and discrete polyoxometalates with an emphasis on materials science.


Footnote
*  Invited paper.
PACS

71.70.Ch Crystal and ligand fields

81.16.Dn Self-assembly

81.16.Nd Nanolithography

65.80.+n Thermal properties of small particles, nanocrystals, nanotubes

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 1 (January–March 2008)

Received 27 September 2007, accepted for publication 17 December 2007

Published 13 March 2008



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