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Low noise laser-based T-ray spectroscopy of liquids using double-modulated differential time-domain spectroscopy

Samuel Peter Mickan1,4, Regina Shvartsman2, Jesper Munch3, Xi-Cheng Zhang2 and Derek Abbott1

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Liquid transmission studies at terahertz frequencies (0.1–10 THz) are valuable for understanding solvation dynamics of salts, exploring long-range structure in mixtures and probing biomolecules in suspension. T-ray (or THz) time-domain spectroscopy, based on terahertz pulse generation from ultrafast lasers, is a sensitive technique for measuring material parameters in this frequency range. This paper proposes and demonstrates a novel technique for increasing the sensitivity and repeatability of liquid studies with T-ray time-domain spectroscopy (TDS), reducing relative parameter measurement errors below 0.0001. The proposed technique combines dual-thickness liquid measurement with rapid modulation (double-modulated differential TDS) to reduce the effect of both thickness-measurement errors and T-ray noise errors below 0.0001. The possible reduction in error is calculated and a liquid differential TDS (DTDS) prototype is demonstrated, incorporating amplitude and mean detection for near-simultaneous measurement of two T-ray waveforms.


PACS

07.57.Pt Submillimeter wave, microwave and radiowave spectrometers; magnetic resonance spectrometers, auxiliary equipment, and techniques

42.62.Fi Laser spectroscopy

61.25.-f Studies of specific liquid structures

Subjects

Soft matter, liquids and polymers

Instrumentation and measurement

Optics, quantum optics and lasers

Dates

Issue 8 (August 2004)

Received 15 December 2003, accepted for publication 22 March 2004

Published 27 July 2004



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