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Analytic solution for quantum control of atomic and molecular wavepackets

FEATURED ARTICLE REVIEW ARTICLE

Luís E E de Araujo1 and Ian A Walmsley2

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PhD TUTORIAL

In this article, we review a different approach to controlling quantum systems. We show that the quantum control problem can be greatly simplified by limiting the duration of the driving force to less than one characteristic period of the system. (For an atomic-electron Rydberg wavepacket this would be the Kepler period, for example, or the vibrational period in the case of a molecule.) If the target state is a bound state of the system, then for times less than the characteristic period, the particle does not have the opportunity to reach the system's boundary and acts essentially as a classical free particle. Such a restriction on the duration of the driving field allows an analytic solution to be found, even in the nonperturbative regime, helping clarify some of the differences between the perturbative and the nonperturbative regimes of excitation. We also show that our solution is nonunique, and the quantum controller has a multiplicity of solutions to chose from.


PACS

03.65.Ge Solutions of wave equations: bound states

02.30.Yy Control theory

34.50.-s Scattering of atoms and molecules

33.20.Tp Vibrational analysis

Subjects

Atomic and molecular physics

Mathematical physics

Quantum information and quantum mechanics

Dates

Issue 1 (February 2003)

Received 3 October 2002

Published 9 December 2002



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