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Theoretical modelling of nonlinear refraction and two-photon absorption in single-wall carbon nanotube bundles

Vl A Margulis1,3 and E A Gaiduk2

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The nonlinear refractive index n2 and the two-photon absorption coefficient α2 are calculated for a bundle of diameter-distributed and aligned single-wall carbon nanotubes. The dispersion of the nanotube circumference length is shown to have important effects on the resonant behaviour of both quantities under consideration, giving rise to a strong broadening, intensity decrease, and `red' shift of the position of the positive and negative resonant peaks in the n2(ω) and α2(ω) spectra. It is predicted that a relatively large refractive-index change (~ 1 cm2 GW-1) from a positive to a negative peak value produced by a relatively small variation of pump frequency can be achieved for real samples of carbon nanotubes in the frequency range where they are almost transparent. The results indicate that carbon nanotubes are a promising novel class of nanoscale materials that could be used in practical optical switching applications.


PACS

78.67.Ch Nanotubes

78.20.Ci Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)

42.70.Nq Other nonlinear optical materials; photorefractive and semiconductor materials

42.65.An Optical susceptibility, hyperpolarizability

Subjects

Condensed matter: electrical, magnetic and optical

Optics, quantum optics and lasers

Nanoscale science and low-D systems

Dates

Issue 4 (July 2001)

Received 26 February 2001, in final form 29 May 2001



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