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Molecular engineering of organic materials for nonlinear absorption in the visible range: the excited states of tetraphenyl-diamine derivatives

Barbara Paci1,4, Jean-Michel Nunzi1, Rémi Anémian2, Chantal Andraud2, André Collet2, Yannick Morel3 and Patrice L Baldeck3

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We report on nonlinear absorption measurements of tetraphenyl-diamine dyes developed for use as transparent materials for optical limiting applications in the visible range. All the excited state properties which are relevant to the process are investigated experimentally using three different and complementary nonlinear spectroscopy tools. Through a modification of the substitution of the peripheral benzene rings of the original dye, we could significantly improve its optical limiting activity, especially in the red region where it had a rather poor efficiency.


PACS

07.60.Fs Polarimeters and ellipsometers

78.40.Me Organic compounds and polymers

42.65.Hw Phase conjugation; photorefractive and Kerr effects

42.79.-e Optical elements, devices, and systems

42.70.Nq Other nonlinear optical materials; photorefractive and semiconductor materials

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Instrumentation and measurement

Optics, quantum optics and lasers

Dates

Issue 4 (July 2000)

Received 14 December 1999



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