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Effect of lanthanoid organometallic compounds on holographic storage characteristics of doped PQ/poly(hydroxyethyl methacrylate-co-methyl methacrylate) hybrids

Yu-Fang Chen1, Yi-Nan Hsiao2,4, Shiuan Huei Lin3, Ken Y Hsu2, Wei-Sheng Cheng1 and Wha-Tzong Whang1,4

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In this research, we fabricate and characterize lanthanide organometallic compounds and 9,10-phenanthrenequinone (PQ) co-doped poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) photopolymers for holographic recording. Five different lanthanoid (Ce3+, Nd3+, Er3+, Yb3+ and Lu3+) organometallic compounds, one at a time, is co-doped with PQ in a poly(HEMA-co-MMA) matrix, respectively. Holographic experiments demonstrate that lutetium organometallic compounds and a PQ co-doped poly(HEMA-co-MMA) photopolymer can greatly enhance the volume holographic characteristics. The degree of improvement in hologram diffraction efficiency and the recording dynamic range for these co-doped photopolymers follows the order: Lu3+>Yb3+>Er3+>Nd3+>Ce3+.


PACS

42.40.Lx Diffraction efficiency, resolution, and other hologram characteristics

42.79.Vb Optical storage systems, optical disks

42.70.Jk Polymers and organics

42.70.Ln Holographic recording materials; optical storage media

Subjects

Soft matter, liquids and polymers

Optics, quantum optics and lasers

Dates

Issue 12 (December 2009)

Received 30 April 2009, accepted for publication 7 August 2009

Published 21 September 2009



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