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Low energy chemical sputtering of ATJ graphite by atomic and molecular deuterium ions

F W Meyer1, P S Krstic1, L I Vergara1, H F Krause1, C O Reinhold1 and S J Stuart2

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We present experimental chemical sputtering results for D+, D2+ and D3+ ions incident on ATJ graphite in the energy range 5–60 eV D−1, and compare them with simulations for deuterated amorphous carbon impacted by neutral D, D2 and D3. The measured methane yields/D for the different species compared at the same energy/D diverge below about 60 eV D−1, the incident triatomic molecular ions leading to the largest yields/D, and the atomic ions to the smallest, reaching a factor of two difference at 10 eV/D. The measured yields/D are in reasonable agreement with molecular dynamics simulations over the entire calculated energy range. The model surfaces were prepared by D, D2 and D3 impacts in a way that mimics the experiment. For D2 incident at energies below 15 eV/D, the simulations show a strong dependence of the sputtering yields on the vibrational state of the incident projectile.


PACS

79.20.Rf Atomic, molecular, and ion beam impact and interactions with surfaces

68.49.Sf Ion scattering from surfaces (charge transfer, sputtering, SIMS)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue T128 (March 2007)

Received 10 October 2006, in final form 14 December 2006

Published 8 March 2007



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