M K Rabinal and B G Mulimani 2007 New J. Phys. 9 440 doi:10.1088/1367-2630/9/12/440
M K Rabinal1 and B G Mulimani2
Show affiliations1-Dodecyne organic molecules (OMs) were chemically bonded to porous silicon (PS) to constitute Si–PS–OMs–metal (M) junctions. PS, which is highly susceptible to atmospheric contamination, becomes stable upon chemical passivation of its surface atoms. Current–voltage curves were studied to understand the charge transport properties, and these measurements indicate clearly that organic passivation unpins the Fermi-level at the PS–M interface. It was believed earlier that Si–PS is the only important interface that controls charge transport in these junctions. We observe that both PS–M and Si–PS interfaces are equally important in influencing the junction parameters when surface states are passivated. The results are discussed in terms of energy band diagrams of these junctions.
73.30.+y Surface double layers, Schottky barriers, and work functions
73.20.At Surface states, band structure, electron density of states
Issue 12 (December 2007)
Received 25 September 2007
Published 12 December 2007
M K Rabinal and B G Mulimani 2007 New J. Phys. 9 440
A T Zayak et al 2003 J. Phys.: Condens. Matter 15 159
Åsa Larson et al 2009 J. Phys.: Conf. Ser. 192 012019
Stephen L Adler 2008 J. Phys. A: Math. Theor. 41 412002
Florian Girelli et al 2002 Class. Quantum Grav. 19 1093
Jian Ye et al 2009 J. Phys.: Conf. Ser. 190 012104
C C Nimmon et al 1975 Phys. Med. Biol. 20 67
M Weber et al 1991 Supercond. Sci. Technol. 4 S403
2009 J. Radiol. Prot. 29 553
M W Hamilton 2007 Eur. J. Phys. 28 341