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Deutsche Physikalische Gessellschaft IOP Institute of Physics

Narrow diameter double-wall carbon nanotubes: synthesis, electron microscopy and inelastic light scattering

Focus on Carbon Nanotubes

R R Bacsa1, E Flahaut1, Ch Laurent1, A Peigney1, S Aloni2, P Puech3 and W S Bacsa3

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Part of Focus on Carbon Nanotubes

Double-wall carbon nanotubes are the molecular analogues to coaxial cables. Narrow diameter double-walled carbon nanotubes (DWNTs) have been obtained by catalytic chemical vapour deposition process with high yield and characterized by scanning and transmission electron microscopy. We examine the inelastic light scattering spectrum of mostly DWNTs with internal tubes of subnanometre diameter. We observe particularly narrow radial breathing modes corresponding to the internal tubes of diameter less than 0.7 nm of double-walled tubes. The D band is found to be strongly helicity dependent and the tangential modes in narrow diameter DWNTs are found to be often down-shifted.


PACS

81.07.De Nanotubes

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.15.Gh Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, etc.)

78.67.Ch Nanotubes

81.16.Be Chemical synthesis methods

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (October 2003)

Received 2 July 2003

Published 9 October 2003



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