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Deutsche Physikalische Gessellschaft IOP Institute of Physics

Kondo-effect of substitutional cobalt impurities at copper surfaces

P Wahl1, A P Seitsonen2, L Diekhöner1,4, M A Schneider1,5 and K Kern1,3

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The influence of the coordination on the Kondo temperature of a magnetic impurity at a noble metal surface and the line shape observed in low temperature scanning tunneling spectroscopy (STS) is investigated for single cobalt atoms adsorbed on and embedded in copper surfaces. Surprisingly, the Kondo temperature for substitutional cobalt atoms is almost the same as that of adatoms on the Cu(100) surface. This is in stark contrast to the behaviour observed at the Cu(111) surface. DFT calculations reveal that in the case of Cu(100) the coupling of the spin of the cobalt atom to the conduction band is not substantially increased by the incorporation of the cobalt atom. At the same time the observed line shape differs strongly from what is observed on adatom systems.


PACS

75.30.Mb Valence fluctuation, Kondo lattice, and heavy-fermion phenomena

75.30.Hx Magnetic impurity interactions

75.70.Rf Surface magnetism

73.20.Hb Impurity and defect levels; energy states of adsorbed species

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

68.43.-h Chemisorption/physisorption: adsorbates on surfaces

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 11 (November 2009)

Received 23 July 2009

Published 6 November 2009



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