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Deutsche Physikalische Gessellschaft IOP Institute of Physics

Image-potential states on the metallic (111) surface of bismuth

Matthias Muntwiler1 and X-Y Zhu

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An extended series (up to n=6, in quantum beats) of image-potential states (IPS) is observed in time-resolved two-photon photoelectron (TR-2PPE) spectroscopy of the Bi(111) surface. Although mainly located in the vacuum, these states probe various properties of the electronic structure of the surface as reflected in their energetics and dynamics. Based on the observation of IPS a projected gap in the surface normal direction is inferred in the region from 3.57 to 4.27 eV above the Fermi level. Despite this band gap, the lifetimes of the IPS are shorter than on comparable metals, which is an indication of the metallic character of the Bi(111) surface.


PACS

73.20.At Surface states, band structure, electron density of states

78.47.-p Spectroscopy of solid state dynamics

79.60.Bm Clean metal, semiconductor, and insulator surfaces

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 11 (November 2008)

Received 8 August 2008

Published 14 November 2008



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