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Deutsche Physikalische Gessellschaft IOP Institute of Physics

Interplay between electronic states and structure during Au faceting

F Schiller1, M Corso2, J Cordón1, F J García de Abajo3 and J E Ortega1,2,3,4

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Au(111) vicinal surfaces are characteristic examples of two-phase segregation or faceting. Between ~4° and 9.5° miscut, the surface exhibits hill-and-valley structures formed by bunches of relatively wide (dw~36–41 Å) and narrow (dn~14 Å) terraces. The evolution of surface electronic states in such a faceted system is followed using a curved crystal. Beyond 4° the surface state splits into distinct dw and dn bands. Our analysis suggests the crucial role of surface states in defining the characteristic dw and dn sizes during Au faceting.


PACS

73.20.At Surface states, band structure, electron density of states

68.35.B- Structure of clean surfaces (and surface reconstruction)

68.47.De Metallic surfaces

Subjects

Surfaces, interfaces and thin films

Dates

Issue 11 (November 2008)

Received 21 July 2008

Published 14 November 2008



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