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Scanning tunnelling microscopy and spectroscopy investigation of rubidium-induced Mott–Hubbard transition on 1T–TaS2

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Published 21 January 2008 Published under licence by IOP Publishing Ltd
, , Citation P Schmidt et al 2008 New J. Phys. 10 013022 DOI 10.1088/1367-2630/10/1/013022

1367-2630/10/1/013022

Abstract

The influence of rubidium deposition on structural and electronic properties of 1T–TaS2 was investigated by scanning tunnelling microscopy and spectroscopy at room temperature. The hexagonally ordered charge density wave (CDW) of the clean surface exhibits a rectangular symmetry upon rubidium adsorption. The spectroscopy data signals a Mott–Hubbard phase transition by an energy gap between upper and lower Hubbard bands giving rise to a Coulomb interaction energy of 1 eV. Owing to spatially resolved spectroscopy the energy gap can be directly related to the rectangular CDW phase. In addition, rubidium adsorption leads to the formation of a network of linear wires. Scanning tunnelling spectroscopy indicates that the wires are most likely not fabricated from rubidium.

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10.1088/1367-2630/10/1/013022