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A simple route to synthesize ZnFe2O4 hollow spheres and their magnetorheological characteristics

Wanquan Jiang1,3, Zhen Cao1, Rui Gu2, Xingzhu Ye2, Cuifeng Jiang1 and Xinglong Gong2,3

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In this paper, a simple route to synthesize hollow spheres of ZnFe2O4 without the assistance of a template is reported. The crystal structure and morphology of these particles were characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), and field emission scanning electron microscopy (FE-SEM). It was found that the final products were hollow spheres with perfect morphology, and their size and the thickness of their shells decreased with the increase of urea precursor. Ferromagnetism was observed from the magnetic hysteresis loops of the ZnFe2O4 hollow spheres at room temperature. The possible formation mechanism of the hollow spheres is discussed. In addition, ZnFe2O4 magnetorheological (MR) fluids were prepared and then their MR effect was investigated on a rotational rheometer equipped with a magnetic field generator.


PACS

81.20.-n Methods of materials synthesis and materials processing

61.66.Fn Inorganic compounds

61.50.-f Structure of bulk crystals

83.80.Gv Electro- and magnetorheological fluids

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

75.50.Dd Nonmetallic ferromagnetic materials

Subjects

Soft matter, liquids and polymers

Fluid dynamics

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 12 (December 2009)

Received 3 July 2009, in final form 3 September 2009

Published 6 October 2009



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