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Characterization of thermally evaporated thin films of Rhodamine 6G

S K Tripathi, Alka Monga and G S S Saini

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The present paper reports the study of Rhodamine 6G (R6G) in thin film form and its structural, optical and electrical characterization. The R6G films are found to have an amorphous structure as determined using the x-ray diffraction technique. The FTIR spectra of R6G thin film confirms that this molecule does not dissociate on being thermally evaporated and thus this technique can be used to deposit the thin films. The fluorescence and transmission spectra, of the thin film, show a redshift in peaks. Temperature dependence of dark conductivity (σd) and photoconductivity (σph) measurements, in the temperature range 303–403 K, confirms that the conduction in R6G is through an activated process having a single activation energy. The photoactivation energy (Eph) value is smaller in comparison to the activation energy in dark (Ed).


PACS

68.55.-a Thin film structure and morphology

78.66.Qn Polymers; organic compounds

78.30.Jw Organic compounds, polymers

73.50.Pz Photoconduction and photovoltaic effects

61.05.cp X-ray diffraction

73.61.Ph Polymers; organic compounds

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 12 (December 2009)

Received 27 January 2009, in final form 26 June 2009

Published 6 October 2009



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