F Neves et al 2009 Smart Mater. Struct. 18 115003 doi:10.1088/0964-1726/18/11/115003
F Neves1,2,7, F M Braz Fernandes1, I Martins2, J B Correia2, M Oliveira2, E Gaffet3, T-Y Wang4, M Lattemann5,6, J Suffner5,6 and H Hahn5,6
Show affiliationsThe phase transformation behaviour of bulk nanostructured NiTi shape memory alloys, produced by an innovative approach called MARES (mechanically activated reactive extrusion synthesis), was investigated using in situ x-ray diffraction and differential scanning calorimetry measurements. For the experimental conditions used, a suitable adjustment of the NiTi matrix composition was achieved after ageing at 500 °C for 7 h. The aged materials showed a homogeneous dispersion of Ni4Ti3 precipitates embedded in a B2-NiTi matrix. Under this condition the B2-NiTi matrix has undergone a
two-stage phase transformation. This was attributed to the complex microstructural evolution during MARES processing, i.e. formation of large-scale and small-scale heterogeneities. Transmission electron microscopy investigations of the solution-treated materials showed the existence of equiaxed nanocrystals in the nanocrystalline NiTi matrix.
64.70.Nd Structural transitions in nanoscale materials
81.30.Kf Martensitic transformations
81.30.Mh Solid-phase precipitation
Issue 11 (November 2009)
Received 22 April 2009, in final form 16 July 2009
Published 11 September 2009
F Neves et al 2009 Smart Mater. Struct. 18 115003
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