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The transformation behaviour of bulk nanostructured NiTi alloys

F Neves1,2,7, F M Braz Fernandes1, I Martins2, J B Correia2, M Oliveira2, E Gaffet3, T-Y Wang4, M Lattemann5,6, J Suffner5,6 and H Hahn5,6

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The phase transformation behaviour of bulk nanostructured NiTi shape memory alloys, produced by an innovative approach called MARES (mechanically activated reactive extrusion synthesis), was investigated using in situ x-ray diffraction and differential scanning calorimetry measurements. For the experimental conditions used, a suitable adjustment of the NiTi matrix composition was achieved after ageing at 500 °C for 7 h. The aged materials showed a homogeneous dispersion of Ni4Ti3 precipitates embedded in a B2-NiTi matrix. Under this condition the B2-NiTi matrix has undergone a \mathrm {B2 \leftrightarrow R \leftrightarrow
B19'} two-stage phase transformation. This was attributed to the complex microstructural evolution during MARES processing, i.e. formation of large-scale and small-scale heterogeneities. Transmission electron microscopy investigations of the solution-treated materials showed the existence of equiaxed nanocrystals in the nanocrystalline NiTi matrix.


PACS

64.70.Nd Structural transitions in nanoscale materials

81.30.Kf Martensitic transformations

81.70.Pg Thermal analysis, differential thermal analysis (DTA), differential thermogravimetric analysis

81.30.Mh Solid-phase precipitation

62.20.F- Deformation and plasticity

81.40.Gh Other heat and thermomechanical treatments

Subjects

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 22 April 2009, in final form 16 July 2009

Published 11 September 2009



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