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Multifunctional layer-by-layer carbon nanotube–polyelectrolyte thin films for strain and corrosion sensing

Kenneth J Loh1, Junhee Kim1, Jerome P Lynch1,2,5, Nadine Wong Shi Kam3,4 and Nicholas A Kotov4

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Since the discovery of carbon nanotubes, researchers have been fascinated by their mechanical and electrical properties, as well as their versatility for a wide array of applications. In this study, a carbon nanotube–polyelectrolyte composite multilayer thin film fabricated by a layer-by-layer (LbL) method is proposed to develop a multifunctional material for measuring strain and corrosion processes. LbL fabrication of carbon nanotube composites yields mechanically strong thin films in which multiple sensing transduction mechanisms can be encoded. For example, judicious selection of carbon nanotube concentrations and polyelectrolyte matrices can yield thin films that exhibit changes in their electrical properties to strain and pH. In this study, experimental results suggest a consistent trend between carbon nanotube concentrations and strain sensor sensitivity. Furthermore, by simply altering the type of polyelectrolyte used, pH sensors of high sensitivity can be developed to potentially monitor environmental factors suggesting corrosion of metallic structural materials (e.g. steel, aluminum).


PACS

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

68.55.A- Nucleation and growth

07.07.Mp Transducers

Subjects

Instrumentation and measurement

Surfaces, interfaces and thin films

Dates

Issue 2 (April 2007)

Received 19 May 2006, in final form 14 December 2006

Published 9 February 2007



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