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Scanning tunneling microscopy investigation of nonanuclear [3 × 3] MnII supramolecular grids

J G Shapter1, L Weeks1, L K Thompson2, K J Pope3, Z Xu2 and M R Johnston1

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A scanning tunneling microscopy (STM) study of [3 × 3] MnII supramolecular grids on Au(111) substrates is presented. Two-dimensional ordering via self-assembly is observed at various coverages. Submolecular resolution is attained with solvent deposition of low concentration samples upon freshly exposed substrates. A comparison of submolecular contrast in STM images is conducted and the importance of suitable image processing techniques is demonstrated in resolving the layer structure of obtained high coverage data.


PACS

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

81.15.-z Methods of deposition of films and coatings; film growth and epitaxy

Subjects

Surfaces, interfaces and thin films

Dates

Issue 1 (February 2006)

Received 6 June 2005

Published 13 December 2005



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