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Determination of gas temperature and thermometric species in inductively coupled plasmas by emission and diode laser absorption

Alexander A Bol'shakov1, Brett A Cruden and Surendra P Sharma

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A vertical cavity surface-emitting laser diode (VCSEL) was used as a spectrally tunable emission source for measurements of the radial-integrated gas temperature inside an inductively coupled plasma reactor. The data were obtained by profiling the Doppler-broadened absorption of metastable Ar atoms at 763.51 nm in argon and argon/nitrogen plasmas (3%, 45%, and 90% N2 in Ar) at pressures of 0.5–70 Pa and inductive powers of 100 and 300 W. The results were compared to the rotational temperature derived from the N2 emission at the (0,0) vibrational transition of the C 3ΠuB 3Π g system. The differences in integrated rotational and Doppler temperatures were attributed to non-uniform spatial distributions of both temperature and thermometric species (Ar* and {\rm N}_{2}^* ) that varied depending on the conditions. A two-dimensional, three-temperature fluid plasma simulation was employed to explain these differences. This work should facilitate further development of a miniature sensor for non-intrusive acquisition of data (temperature and densities of multiple plasma species) during micro- and nano-fabrication plasma processing, thus enabling diagnostic-assisted continuous optimization and advanced control over the processes. Such sensors would also enable us to track the origins and pathways of damaging contaminants, thereby providing real-time feedback for adjustment of processes. Our work serves as an example of how two line-of-sight integrated temperatures derived from different thermometric species make it possible to characterize the radial non-uniformity of the plasma.


PACS

52.38.Dx Laser light absorption in plasmas (collisional, parametric, etc.)

32.70.Jz Line shapes, widths, and shifts

52.25.Os Emission, absorption, and scattering of electromagnetic radiation

52.65.Kj Magnetohydrodynamic and fluid equation

52.25.Kn Thermodynamics of plasmas

Subjects

Atomic and molecular physics

Plasma physics

Dates

Issue 4 (November 2004)

Received 20 May 2004

Published 28 October 2004



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