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Emission in the deep vacuum ultraviolet from a plasma formed by incandescently heating hydrogen gas with trace amounts of potassium carbonate

H Conrads1, R Mills2 and Th Wrubel3

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A hydrogen plasma with intense extreme ultraviolet and visible emission was generated from low pressure hydrogen gas (0.1–1 mbar) in contact with a hot tungsten filament only when the filament heated a titanium dissociator coated with K2CO3 above 750°C. The electric field strength from the filament was about 1 V cm−1, two orders of magnitude lower than the starting voltages measured for gas glow discharges. The emission of the Hα and Hβ transitions as well as the Lα and Lβ transitions were recorded and analysed. The plasma seemed to be far from thermal equilibrium, and no conventional mechanism was found to explain the formation of a hydrogen plasma by incandescently heating hydrogen gas in the presence of trace amounts of K2CO3. The temporal behaviour of the plasma was recorded via hydrogen Balmer alpha line emission when all power into the cell was terminated and an excessive afterglow duration (2 s) was observed. The plasma was found to be dependent on the chemistry of atomic hydrogen with potassium since no plasma formed with Na2CO3 replacing K2CO3 and the time constant of the emission following the removal of all of the power to the cell matched that of the cooling of the filament and the resulting shift from atomic to molecular hydrogen. Our results indicate that a novel chemical power source is present and that it forms the energetic hydrogen plasma that is a potential new light source.


PACS

52.80.Hc Glow; corona

52.50.-b Plasma production and heating

52.25.Os Emission, absorption, and scattering of electromagnetic radiation

82.33.Xj Plasma reactions (including flowing afterglow and electric discharges)

Subjects

Plasma physics

Chemical physics and physical chemistry

Dates

Issue 3 (August 2003)

Received 11 January 2002, in final form 3 April 2003

Published 2 June 2003



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