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Generation of metal-oxide nanoparticles using continuous-wave fibre laser ablation in liquid

Z Liu1, Y Yuan1, S Khan1, A Abdolvand2, D Whitehead2, M Schmidt2 and L Li2

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In recent years, laser ablation in liquid has become an increasingly important technique for the fabrication of nanoparticles (NPs). To date, only pulsed lasers have been used. This paper reports our recent studies on the generation of Ti-oxide and Ni-oxide NPs by the ablation of metal targets in aqueous environments using a high-power, high-brightness continuous-wave (cw) fibre laser at a wavelength of 1070 nm. Owing to the high and uniform irradiation, the fibre laser provides an alternative approach for NP generation with well-controlled phase, size and size distribution, along with high production rate. Characterization of the NPs, in terms of morphology, size and size distribution, chemical composition and phase structure, by means of high-resolution transmission electron microscopy (HRTEM), high-angle annular dark field (HAADF) in scanning-transmission (STEM) mode, energy-dispersive x-ray spectroscopy (EDS) and x-ray diffraction (XRD), has been presented. In addition, limitations of the cw fibre laser process have been discussed in comparison with pulsed laser process.


PACS

81.07.-b Nanoscale materials and structures: fabrication and characterization

61.80.Ba Ultraviolet, visible, and infrared radiation effects (including laser radiation)

68.37.Lp Transmission electron microscopy (TEM)

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

61.05.cp X-ray diffraction

Subjects

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 5 (May 2009)

Received 16 September 2008, in final form 23 December 2008

Published 14 April 2009



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