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Application of hydrogel-coated microcantilevers as sensing elements for pH

Julian Gonska1, Christoph Schelling1 and Gerald Urban2,3

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TECHNICAL NOTE

This note reports on cantilever-based sensor elements coated with a hydrogel. The hydrogel responds with a volume change on varying the pH value of surrounding liquids. The change in volume leads to a static deflection of the cantilevers, which is detected using integrated piezoresistors. To increase deflection sensitivity of the sensor elements, sub-micron, multilayered cantilevers consisting of polycrystalline silicon and silicon oxide are used. A new cantilever design is developed, which decreases the cantilever sensitivity to in situ stresses and thermal bimorph effects. A theoretical model for the sensor elements is introduced providing the output signal of multiple cantilevers connected in a full Wheatstone bridge. Measurements of deflection sensitivity prove the theoretical model. Finally, the cantilevers are coated with a 2-hydroxyethyl methacrylate and 2-(dimethylamino) ethyl methacrylate copolymer-based hydrogel, and changes in the pH value from pH 4 to pH 10 are measured.


PACS

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

82.70.Gg Gels and sols

84.32.Ff Conductors, resistors (including thermistors, varistors, and photoresistors)

85.85.+j Micro- and nano-electromechanical systems (MEMS/NEMS) and devices

82.80.-d Chemical analysis and related physical methods of analysis

82.33.Ln Reactions in sol gels, aerogels, porous media

Subjects

Soft matter, liquids and polymers

Electronics and devices

Instrumentation and measurement

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 12 (December 2009)

Received 1 September 2009

Published 11 November 2009



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