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The fabrication of a microcolumn for gas separation using poly(dimethylsiloxane) as the structural and functional material

A Malainou, M E Vlachopoulou, R Triantafyllopoulou, A Tserepi and S Chatzandroulis

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The fabrication and performance of a microcolumn made of poly(dimethylsiloxane) (PDMS) for gas separation is presented. PDMS is a material commonly used as a stationary phase in large-scale chromatography systems, while in this work it serves both as the structural material of the microcolumn as well as a stationary phase enabling gas mixture separation by different absorption and desorption kinetics of the sample components on the column walls. Gas separation is demonstrated for a xylene/benzene vapor mixture at different ratios detected by means of a VOC sensor connected at the exit of the microcolumn. The effect of the microcolumn depth and working temperature on the separation performance of the microcolumn is investigated.


PACS

82.80.Bg Chromatography

68.43.Mn Adsorption kinetics

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

85.40.Hp Lithography, masks and pattern transfer

Subjects

Electronics and devices

Instrumentation and measurement

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 10 (October 2008)

Received 22 April 2008, in final form 28 July 2008

Published 5 September 2008



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