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Making electrical contact to single molecules

Wolfgang Fritzsche-+, Konrad Böhm++, Eberhard Unger++ and J Michael Köhler

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We are interested in the characterization of electron transport phenomenon through single (bio)molecules. A prerequisite for electrical measurements is the contacting of molecules in the nanometer range. This paper describes various steps toward this goal, starting from statistically distributed molecules (namely, microtubules) adsorbed on a microstructured surface. Monitored by scanning force microscopy and video-enhanced microscopy, adsorption parameters were studied and optimized, including protein-mediated adsorption, induced orientation, and controlled desorption. Line structures connecting the adsorbed molecules to prestructured electrodes were created by means of electron beam-induced deposition (EBD) in a scanning electron microscope. It is shown how such EBD lines can be used as masks for the structuring of metal contacts, and an electrical characterization of these contacts is given.


PACS

87.16.Ka Filaments, microtubules, their networks, and supramolecular assemblies

87.15.-v Biomolecules: structure and physical properties

87.64.Dz Scanning tunneling and atomic force microscopy

68.43.Mn Adsorption kinetics

87.14.E- Proteins

Subjects

Surfaces, interfaces and thin films

Medical physics

Biological physics

Dates

Issue 3 (September 1998)

Received 30 March 1998



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