Sebastian Strobel et al 2010 Nanotechnology 21 505301 doi:10.1088/0957-4484/21/50/505301
Sebastian Strobel1, Christopher Kirkendall1,2, Jae-Byum Chang1 and Karl K Berggren1
Show affiliationsA study of the dewetting behavior of platinum-thin-films on silicon was carried out to determine how variation of dewetting parameters affects the evolution of film morphology and to pinpoint which parameters yielded the smallest, most circular features. Platinum film thickness as well as dewetting time and temperature were varied and the film morphology characterized by means of scanning electron microscopy (SEM) analysis. Two different pathways of dewetting predicted in the literature (Vrij 1966 Discuss. Faraday Soc. 42 23, Becker et al 2003 Nat. Mater. 2 59–63) were observed. Depending on the initial criteria, restructuring of the film occurred via hole or droplet formation. With increased annealing time, a transition from an intermediate network structure to separated islands occurred. In addition, the formation of multilayered films, silicide crystals and nanowires occurred for certain parameters. Nevertheless, the dewetting behavior witnessed could be related to physical processes. Droplets with a mean diameter of 9 nm were formed by using a 1.5 nm thick platinum film annealed at 800 °C for 30 s. To demonstrate the suitability of the annealed films for further processing, we then used the dewetted films as masks for reactive ion etching to transfer the pattern into the silicon substrate, forming tapered nanopillars.
68.55.-a Thin film structure and morphology
61.46.-w Structure of nanoscale materials
81.65.Cf Surface cleaning, etching, patterning
Soft matter, liquids and polymers
Surfaces, interfaces and thin films
Issue 50 (17 December 2010)
Received 31 August 2010, in final form 21 October 2010
Published 22 November 2010
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