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Spatially resolved Raman spectroscopy on indium-catalyzed core–shell germanium nanowires: size effects

Y Xiang1, I Zardo1, L Y Cao2, T Garma1,3, M Heiß1,3, J R Morante4,5, J Arbiol4,6, M L Brongersma2 and A Fontcuberta i Morral1,3

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The structure of indium-catalyzed germanium nanowires is investigated by atomic force microscopy, scanning confocal Raman spectroscopy and transmission electron microscopy. The nanowires are formed by a crystalline core and an amorphous shell. We find that the diameter of the crystalline core varies along the nanowire, down to few nanometers. Phonon confinement effects are observed in the regions where the crystalline region is the thinnest. The results are consistent with the thermally insulating behavior of the core–shell nanowires.


PACS

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

61.46.-w Structure of nanoscale materials

78.30.Am Elemental semiconductors and insulators

68.37.Lp Transmission electron microscopy (TEM)

68.37.Ps Atomic force microscopy (AFM)

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 10 (12 March 2010)

Received 21 August 2009, in final form 10 November 2009

Published 15 February 2010



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