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Bias-dependent amino-acid-induced conductance changes in short semi-metallic carbon nanotubes

G B Abadir, K Walus and D L Pulfrey

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We study the interaction between short semi-metallic carbon nanotubes and different amino acids using molecular dynamics and ab initio (density functional theory/non-equilibrium Green's function) simulations. We identify two different mechanisms of nanotube conductance change upon adsorption of amino acids: one due to the change of the coordinates of the nanotube arising from van der Waals forces of interaction with the adsorbed amino acid; and one due to electrostatic interactions, which appear only in the case of charged amino acids. We also find that the transport mechanism and the changes in the conductance of the tube upon amino acid adsorption are bias dependent.


PACS

68.43.Mn Adsorption kinetics

73.63.Fg Nanotubes

61.46.Fg Nanotubes

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (8 January 2010)

Received 10 August 2009, in final form 5 November 2009

Published 30 November 2009



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