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Embedded ferroelectric nanostructure arrays

S Clemens1, S Röhrig2, A Rüdiger3, T Schneller1 and R Waser1,2

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Ferroelectrics hold promise for high-density non-volatile data storage device use. Their eventual performance will strongly depend on the available displacement current, which primarily scales with the area but might to some extent be enhanced by substrate-induced homogeneous strain while the interface at the same time controls the coercive field. As the lateral dimensions persistently decrease, the only way to keep track of the real figures of merit with realistic electrodes is to use a macroscopic configuration instead of scanning probe approaches with undefined interfaces. We report on a novel approach to integrating arbitrarily patterned, highly registered ferroelectric nanoislands fabricated by a template controlled chemical solution deposition approach into a matrix of a low-k dielectric spin-on glass. These structures with a narrow lateral size distribution below 100 nm are subsequently polished in a chemical–mechanical polishing step to expose their very tops, whose piezoelectrically active area depends on the polishing time. At this stage our findings indicate a full piezoelectric functionality of the locally exposed nanoislands. The structures are ready for macroscopic top electrodes to average the displacement current over hundreds of almost identical structures, to provide a nanoscale scaling behaviour of the individual ferroelectric capacitors.


PACS

81.16.Be Chemical synthesis methods

77.65.-j Piezoelectricity and electromechanical effects

77.55.+f Dielectric thin films

77.80.-e Ferroelectricity and antiferroelectricity

81.07.-b Nanoscale materials and structures: fabrication and characterization

81.65.Ps Polishing, grinding, surface finishing

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 7 (18 February 2009)

Received 12 November 2008, in final form 19 December 2008

Published 23 January 2009



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