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Rapid thermal annealing effects on tin oxide nanowires prepared by vapor–liquid–solid technique

Ayan Kar1, Jianyong Yang1, Mitra Dutta1,2, Michael A Stroscio1,2,3, Jyoti Kumari4 and M Meyyappan4

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Tin oxide nanowires have been grown on p-type silicon substrates using a gold-catalyst-assisted vapor–liquid–solid growth process. The nanowires were annealed in the presence of oxygen at 700 °C for different time intervals. The changes in material properties of the nanowires after annealing were investigated using various characterization techniques. Annealing improves the crystal quality of the nanowires as seen from Raman spectroscopy analysis. Photoluminescence (PL) data indicates a decrease in the oxygen vacancies and defects after annealing, affecting the luminescence from the nanowires. In addition, x-ray photoelectron spectroscopy (XPS) was used to obtain the changes in the tin and oxygen atomic concentrations before and after annealing, from which the stoichiometry was calculated.


PACS

81.16.Hc Catalytic methods

78.67.Lt Quantum wires

79.60.Jv Interfaces; heterostructures; nanostructures

78.30.Hv Other nonmetallic inorganics

81.40.Gh Other heat and thermomechanical treatments

78.55.Hx Other solid inorganic materials

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 6 (11 February 2009)

Received 2 September 2008, in final form 23 October 2008

Published 15 January 2009



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