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Tailoring the shapes of FexPt100−x nanoparticles

N Shukla1,2,5, M M Nigra3, T Nuhfer4, M A Bartel3 and A J Gellman2,3

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FexPt100−x nanoparticles of varying composition have been synthesized with various shapes and sizes using a high pressure synthesis method which allows control of synthesis conditions, in particular the reaction temperature. Tailoring the shapes and sizes of FexPt1−x nanoparticles allows one to control a variety of properties that are relevant to the many potential applications of metallic nanoparticles. Shape and composition can be used to control catalytic activity and to achieve high packing density in self-assembled films. Variation of both nanoparticle size and shape has been achieved by using various different solvents. The solvents used in the nanoparticle synthesis can influence the product because they can play a role as surfactants. Using solvents of various types it has been possible to synthesize FexPt100−x nanoparticles with a variety of shapes including spherical, rod-like, cubic, hexagonal and high aspect ratio wires. Control of nanoparticle shape opens the door to their being used in various technological applications for which spherical nanoparticles are ineffective.


PACS

81.16.Dn Self-assembly

81.07.-b Nanoscale materials and structures: fabrication and characterization

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

Subjects

Nanoscale science and low-D systems

Dates

Issue 6 (11 February 2009)

Received 12 August 2008, in final form 1 December 2008

Published 15 January 2009



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