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Very long single- and few-walled boron nitride nanotubes via the pressurized vapor/condenser method

Michael W Smith1, Kevin C Jordan2, Cheol Park3, Jae-Woo Kim3, Peter T Lillehei1, Roy Crooks3 and Joycelyn S Harrison4

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A new method for producing long, small-diameter, single- and few-walled, boron nitride nanotubes (BNNTs) in macroscopic quantities is reported. The pressurized vapor/condenser (PVC) method produces, without catalysts, highly crystalline, very long, small-diameter, BNNTs. Palm-sized, cotton-like masses of BNNT raw material were grown by this technique and spun directly into centimeters-long yarn. Nanotube lengths were observed to be 100 times that of those grown by the most closely related method. Self-assembly and growth models for these long BNNTs are discussed.


PACS

81.16.Dn Self-assembly

81.05.Ea III-V semiconductors

61.46.Fg Nanotubes

68.65.-k Low-dimensional, mesoscopic, and nanoscale systems: structure and nonelectronic properties

81.07.De Nanotubes

Subjects

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 50 (16 December 2009)

Received 27 July 2009, in final form 24 October 2009

Published 12 November 2009



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