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Tri- and quadri-metallic ultrathin nanowires synthesized by one-step phase-transfer approach

Wei-Qiang Han1, Dong Su1, Lijun Wu2, Toshihiro Aoki3 and Yimei Zhu2

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We synthesized, at room temperature, noble multi-metallic (Pt–Pd–Rh, and Pt–Pd–Au–Rh) ultrathin nanowires using a one-step phase-transfer approach. These multi-metallic nanowires then were characterized by x-ray diffraction, transmission electron microscopy, and scanning transmission electron microscopy. The diameters of the nanowires range from 2 to 2.7 nm, and their lengths from tens to hundreds of nanometers. The multi-metallic nanowires were determined to be face-centered cubic structures. The compositions of the nanowires are quite uniform from wire to wire. Our results verify that the phase-transfer is a robust method for synthesizing various multi-metallic nanowires, which are expected to have potential applications in catalysis, magnetic storage, and bio-sensors.


PACS

81.16.-c Methods of nanofabrication and processing

81.07.-b Nanoscale materials and structures: fabrication and characterization

68.65.-k Low-dimensional, mesoscopic, and nanoscale systems: structure and nonelectronic properties

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 49 (9 December 2009)

Received 11 September 2009, in final form 14 October 2009

Published 6 November 2009



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