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Controllable growth and magnetic properties of nickel nanoclusters electrodeposited on the ZnO nanorod template

Yang Tang1,2, Dongxu Zhao1,4, Dezhen Shen1, Jiying Zhang1 and Xiaohua Wang3

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The ZnO nanorods were used as a template to fabricate nickel nanoclusters by electrodeposition. The ZnO nanorod arrays act as a nano-semiconductor electrode for depositing metallic and magnetic nickel nanoclusters. The growth sites of Ni nanoclusters could be controlled by adjusting the applied potential. Under −1.15 V the Ni nanoclusters could be grown on the tips of ZnO nanorods. On increasing the potential to be more negative the ZnO nanorods were covered by Ni nanoclusters. The magnetic properties of the electrodeposited Ni nanoclusters also evolved with the applied potentials.


PACS

81.16.-c Methods of nanofabrication and processing

75.50.Tt Fine-particle systems; nanocrystalline materials

75.75.+a Magnetic properties of nanostructures

61.46.Bc Structure of clusters (e.g., metcars; not fragments of crystals; free or loosely aggregated or loosely attached to a substrate)

81.15.Pq Electrodeposition, electroplating

81.05.Dz II-VI semiconductors

Subjects

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 49 (9 December 2009)

Received 14 May 2009, in final form 25 July 2009

Published 6 November 2009



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