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The formation of vertically aligned biaxial tungsten nanorods using a novel shadowing growth technique

R Krishnan1, T Parker2, S Lee3 and T-M Lu2

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Biaxially textured tungsten nanorods (A15 crystal structure) have been grown by oblique angle DC magnetron sputtering using a novel rotation mode called 'two-step rotation'. In this mode, the substrate is given a fast rotation through 180° at 90 rpm and this is followed by a rest period of 30 s. These nanorods are vertically aligned and have a [100] texture normal to the substrate along with preferential in-plane texture as shown by x-ray pole figure analysis. In contrast, the tungsten nanorods obtained without substrate rotation are slanted at an angle of ~45° and have a [100] texture tilted 16° with respect to the substrate normal. The flux is incident from two diametrically opposite points on the sample at an oblique angle, averaging out the growth into vertical columns that retain the in-plane texture. Scanning electron microscopy shows that the tungsten nanorods have a mixture of {211} and {421} crystal habits; these planes are both minimum surface energy planes for a cubic A15 crystal structure.


PACS

81.16.-c Methods of nanofabrication and processing

61.46.-w Structure of nanoscale materials

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.07.-b Nanoscale materials and structures: fabrication and characterization

81.15.Cd Deposition by sputtering

81.05.Bx Metals, semimetals, and alloys

Subjects

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 46 (18 November 2009)

Received 27 August 2009, in final form 28 September 2009

Published 22 October 2009



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