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N–P transition sensing behaviors of ZnO nanotubes exposed to NO2 gas

J X Wang1,2,3, X W Sun1, Y Yang1 and C M L Wu2

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Hydrothermally synthesized ZnO nanotube arrays were used to fabricate the gas sensor for detection of the toxic gas NO2. The ZnO nanotube gas sensor exhibited sensitive response to NO2 down to 500 ppb at low temperature 30 °C. Abnormal temperature-dependent and concentration-dependent N–P transition behaviors were observed. The excellent sensing ability of the sensor and their anomalous conductivity behaviors may be attributed to the unique surface conductivity related to the hollow nanostructure feature. These sensing behaviors may help to comprehensively understand the sensing mechanism of 1D ZnO nanostructures and improve the selectivity of the ZnO gas sensor.


PACS

81.07.De Nanotubes

82.80.-d Chemical analysis and related physical methods of analysis

73.25.+i Surface conductivity and carrier phenomena

61.46.Fg Nanotubes

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 46 (18 November 2009)

Received 7 July 2009, in final form 15 September 2009

Published 21 October 2009



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