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Identifying individual n- and p-type ZnO nanowires by the output voltage sign of piezoelectric nanogenerator

S S Lin1, J H Song1, Y F Lu2 and Z L Wang1

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Based on a comparative study between the piezoelectric outputs of n-type nanowires (NWs) and n-core/p-shell NWs along with the previous study (Lu et al 2009 Nano. Lett. 9 1223), we demonstrate a one-step technique for identifying the conductivity type of individual ZnO nanowires (NWs) based on the output of a piezoelectric nanogenerator without destroying the sample. A negative piezoelectric output voltage indicates an NW is n-type and it appears after the tip scans across the center of the NW, while a positive output voltage reveals p-type conductivity and it appears before the tip scans across the central line of the NW. This atomic force microscopy based technique is reliable for statistically mapping the majority carrier type in ZnO NWs arrays. The technique may also be applied to other wurtzite semiconductors, such as GaN, CdS and ZnS.


PACS

77.65.-j Piezoelectricity and electromechanical effects

73.63.Nm Quantum wires

68.37.Ps Atomic force microscopy (AFM)

81.07.Vb Quantum wires

73.50.Pz Photoconduction and photovoltaic effects

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 36 (9 September 2009)

Received 19 May 2009, in final form 21 July 2009

Published 18 August 2009



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