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The fabrication of a carbon nanotube array using a catalyst-poisoning layer in the inverse nano-sphere lithography method

Tsung-Yen Tsai, Tsung-Han Chen, Nyan-Hwa Tai, Shih-Chin Chang, Hui-Chen Hsu and Thomas Joseph Palathinkal

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A new method for the fabrication of periodic CNT arrays was developed in this study, which involves the use of the inverse nano-sphere lithography (INSL) process. Mo of a honeycomb pattern, acting as a catalyst-poisoning layer, was produced by the nano-sphere lithography (NSL) process; the Mo poisoned the catalyst and prevented CNT growth where deposited, and as a result, a periodic CNT pattern was obtained. Using this method, the uniformity of the CNT array can be improved by preventing the negative effect of arrangement defects in self-assembled monolayers. The size and the period of the CNT array can be adjusted by careful selection of the polystyrene (PS) sphere diameter. X-ray photoelectron spectroscope (XPS) analysis revealed that the Co catalyst was ineffective on the areas of Mo deposition due to the diffusion of Co into the Mo layer.


PACS

81.16.Nd Nanolithography

79.60.Jv Interfaces; heterostructures; nanostructures

66.30.Pa Diffusion in nanoscale solids

81.16.Dn Self-assembly

81.07.De Nanotubes

81.16.Hc Catalytic methods

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 30 (29 July 2009)

Received 16 March 2009, in final form 3 June 2009

Published 7 July 2009



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