Ashwini Gopal et al 2009 Nanotechnology 20 235201 doi:10.1088/0957-4484/20/23/235201
Ashwini Gopal, Kazunori Hoshino, Sunmin Kim and Xiaojing Zhang
Show affiliationsWe present a colloidal quantum dot based light emitting diode (QD-LED) which utilizes the p-type silicon substrate as the hole transporting layer. A microcontact printing technique was introduced to pattern self-assembled CdSe/ZnS QD films, which allowed creation of an LED with well-defined geometry suitable for monolithic integration on silicon substrates. Our QD-LED consists of multi-layers of inorganic materials: a combination of Au (thickness: 5 nm) and Ag (12 nm) as the cathode, a ZnO:SnO2 mixture (ratio 3:1, 40 nm) as the electron transporting layer, CdSe/ZnS QDs as the light emission layer, 1 nm SiO2 as an energy barrier layer, and p-type silicon as the hole transporting layer. These printed QD-LEDs are capable of multi-color emission peaked at wavelengths of 576 nm, 598 nm, and 622 nm, corresponding to sizes of the embedded QDs with the diameters of 8.4 nm, 9.0 nm, and 9.8 nm respectively. The optimal thickness of the quantum dot layers needed for light emission is characterized using atomic force microscopy: for 8.4 nm QDs, the value is 33 nm (± 5 nm) or ~4 ML (monolayers). Larger turn on voltages were measured (2, 4 and 5 V) for the smaller average particle diameters (9.8 nm, 9.0 nm and 8.4 nm, respectively). The mixture ratio of Zn and Sn was optimized (40% Zn and 25% Sn) to maintain proper hole–electron recombination at the QD layer and avoid the yellowish-white emission from ZnO/SnO2.
85.60.Jb Light-emitting devices
85.35.Be Quantum well devices (quantum dots, quantum wires, etc.)
73.50.Gr Charge carriers: generation, recombination, lifetime, trapping, mean free paths
Soft matter, liquids and polymers
Surfaces, interfaces and thin films
Optics, quantum optics and lasers
Issue 23 (10 June 2009)
Received 23 January 2009, in final form 30 March 2009
Published 18 May 2009
Ashwini Gopal et al 2009 Nanotechnology 20 235201
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