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Multi-color colloidal quantum dot based light emitting diodes micropatterned on silicon hole transporting layers

Ashwini Gopal, Kazunori Hoshino, Sunmin Kim and Xiaojing Zhang

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We present a colloidal quantum dot based light emitting diode (QD-LED) which utilizes the p-type silicon substrate as the hole transporting layer. A microcontact printing technique was introduced to pattern self-assembled CdSe/ZnS QD films, which allowed creation of an LED with well-defined geometry suitable for monolithic integration on silicon substrates. Our QD-LED consists of multi-layers of inorganic materials: a combination of Au (thickness: 5 nm) and Ag (12 nm) as the cathode, a ZnO:SnO2 mixture (ratio 3:1, 40 nm) as the electron transporting layer, CdSe/ZnS QDs as the light emission layer, 1 nm SiO2 as an energy barrier layer, and p-type silicon as the hole transporting layer. These printed QD-LEDs are capable of multi-color emission peaked at wavelengths of 576 nm, 598 nm, and 622 nm, corresponding to sizes of the embedded QDs with the diameters of 8.4 nm, 9.0 nm, and 9.8 nm respectively. The optimal thickness of the quantum dot layers needed for light emission is characterized using atomic force microscopy: for 8.4 nm QDs, the value is 33 nm (± 5 nm) or ~4 ML (monolayers). Larger turn on voltages were measured (2, 4 and 5 V) for the smaller average particle diameters (9.8 nm, 9.0 nm and 8.4 nm, respectively). The mixture ratio of Zn and Sn was optimized (40% Zn and 25% Sn) to maintain proper hole–electron recombination at the QD layer and avoid the yellowish-white emission from ZnO/SnO2.


PACS

85.60.Jb Light-emitting devices

82.70.Dd Colloids

85.35.Be Quantum well devices (quantum dots, quantum wires, etc.)

73.50.Gr Charge carriers: generation, recombination, lifetime, trapping, mean free paths

81.16.Nd Nanolithography

85.40.Hp Lithography, masks and pattern transfer

Subjects

Soft matter, liquids and polymers

Electronics and devices

Surfaces, interfaces and thin films

Optics, quantum optics and lasers

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 23 (10 June 2009)

Received 23 January 2009, in final form 30 March 2009

Published 18 May 2009



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