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High-coercivity FePt nanoparticle assemblies embedded in silica thin films

Q Yan1,2,3, A Purkayastha1, A P Singh1, H Li1, A Li2, R V Ramanujan3 and G Ramanath1

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The ability to process assemblies using thin film techniques in a scalable fashion would be a key to transmuting the assemblies into manufacturable devices. Here, we embed FePt nanoparticle assemblies into a silica thin film by sol–gel processing. Annealing the thin film composite at 650 °C transforms the chemically disordered fcc FePt phase into the fct phase, yielding magnetic coercivity values Hc>630 mT. The positional order of the particles is retained due to the protection offered by the silica host. Such films with assemblies of high-coercivity magnetic particles are attractive for realizing new types of ultra-high-density data storage devices and magneto-composites.


PACS

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

75.75.+a Magnetic properties of nanostructures

75.50.Vv High coercivity materials

75.50.Bb Fe and its alloys

81.20.Fw Sol-gel processing, precipitation

75.50.Tt Fine-particle systems; nanocrystalline materials

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 2 (14 January 2009)

Received 2 September 2008, in final form 27 October 2008

Published 11 December 2008



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