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Carrier transport in flexible organic bistable devices of ZnO nanoparticles embedded in an insulating poly(methyl methacrylate) polymer layer

Dong-Ick Son1,2, Dong-Hee Park1, Won Kook Choi1,3, Sung-Hwan Cho2, Won-Tae Kim2 and Tae Whan Kim2

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The bistable effects of ZnO nanoparticles embedded in an insulating poly(methyl methacrylate) (PMMA) polymer single layer by using flexible polyethylene terephthalate (PET) substrates were investigated. Transmission electron microscopy (TEM) images revealed that ZnO nanoparticles were formed inside the PMMA polymer layer. Current–voltage (I–V) measurement on the Al/ZnO nanoparticles embedded in an insulating PMMA polymer layer/ITO/PET structures at 300 K showed a nonvolatile electrical bistability behavior with a flat-band voltage shift due to the existence of the ZnO nanoparticles, indicative of trapping, storing, and emission of charges in the electronic states of the ZnO nanoparticles. The carrier transport mechanism of the bistable behavior for the fabricated organic bistable device (OBD) structures is described on the basis of the I–V results by analyzing the effect of space charge.


PACS

85.35.-p Nanoelectronic devices

81.07.-b Nanoscale materials and structures: fabrication and characterization

85.30.De Semiconductor-device characterization, design, and modeling

73.50.Gr Charge carriers: generation, recombination, lifetime, trapping, mean free paths

73.63.Bd Nanocrystalline materials

81.16.-c Methods of nanofabrication and processing

Subjects

Electronics and devices

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 19 (13 May 2009)

Received 14 January 2009, in final form 23 February 2009

Published 20 April 2009



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