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Selective-area growth of vertically aligned GaAs and GaAs/AlGaAs core–shell nanowires on Si(111) substrate

Katsuhiro Tomioka1,3, Yasunori Kobayashi1, Junichi Motohisa1, Shinjiroh Hara2 and Takashi Fukui1,2

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We report on selective-area growth of vertically aligned GaAs nanowires on Si(111) substrate. Modification of the initial Si(111) surface by pretreatment under an AsH3 atmosphere and low-temperature growth of GaAs were important for controlling the growth orientations of the GaAs nanowire on the Si(111) surface. We also found that the size of openings strongly affected the growth morphology of GaAs nanowires on Si(111). Small diameter openings reduced the antiphase defects and improved the optical properties in the GaAs nanowires. Moreover, we realized coherent growth without misfit dislocation at the GaAs/Si interface. Finally, we demonstrated fabrication of a GaAs/AlGaAs core–shell nanowire array on a Si surface and revealed that the luminescence intensity was markedly enhanced by passivation effects. These results are promising for future III–V nanowire-based optoelectronic integration on Si platforms.


PACS

68.65.La Quantum wires (patterned in quantum wells)

81.07.Vb Quantum wires

81.16.-c Methods of nanofabrication and processing

61.46.-w Structure of nanoscale materials

78.55.Cr III-V semiconductors

78.67.Lt Quantum wires

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 14 (8 April 2009)

Received 18 December 2008, in final form 23 January 2009

Published 17 March 2009



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