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The elastic moduli of oriented tin oxide nanowires

Sven Barth1,2,4, Catalin Harnagea1, Sanjay Mathur2,3 and Federico Rosei1,4

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Tin oxide nanowires (NWs) exhibit interesting electronic properties, which can be harnessed for applications in nanoelectronic devices and sensors. Oriented single crystalline tin oxide NWs were grown at 45° from a titanium dioxide substrate. Their elastic properties were investigated in a two-point geometry using an atomic force microscope (AFM) coupled with a scanning electron microscope under ultrahigh vacuum conditions. Young's modulus was calculated by bending individual NWs and measuring the force exerted on the AFM tip during force–displacement measurements. For the NWs investigated, having radial dimensions below 45 nm and length up to 1.2 µm, we found an average value of 100 ± 20 GPa, which is below the theoretical predictions calculated for different SnO2 single crystal orientations, yet consistent with the indentation moduli of nanobelts. Finally, we discuss the effects of the nanowire–cantilever configuration on the measured Young's modulus.


PACS

62.25.-g Mechanical properties of nanoscale systems

81.40.Jj Elasticity and anelasticity, stress-strain relations

81.16.-c Methods of nanofabrication and processing

62.20.D- Elasticity

Subjects

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 11 (18 March 2009)

Received 10 November 2008, in final form 21 December 2008

Published 25 February 2009



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