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Scalable fabrication of immunosensors based on carbon nanotube polymer composites

Ernest Mendoza1, Jahir Orozco2, Cecilia Jiménez-Jorquera2, Ana B González-Guerrero1, Ana Calle3, Laura M Lechuga3 and César Fernández-Sánchez2

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In this work we present the fabrication and characterization of immunosensors based on polystyrene (PS)–multiwalled carbon nanotube (MWCNT) composites. The electrochemical properties of the sensors have been investigated and show that the surface area is increased upon addition of the MWCNT–PS layer. Furthermore, a plasma activation process is used to partially remove the PS and expose the MWCNTs. This results in a huge increase in the electrochemical area and opens up the possibility of binding biomolecules to the MWCNT wall. The MWCNTs have been functionalized covalently with a model antibody (rabbit IgG). The biosensors have been tested using amperometric techniques and show detection limits comparable to standard techniques such as ELISA.


PACS

87.80.-y Biophysical techniques (research methods)

87.85.Qr Nanotechnologies-design

Subjects

Instrumentation and measurement

Medical physics

Biological physics

Dates

Issue 7 (20 February 2008)

Received 16 November 2007, in final form 19 December 2007

Published 29 January 2008



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