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Sub-wavelength ripples in fused silica after irradiation of the solid/liquid interface with ultrashort laser pulses

R Böhme1, C Vass2, B Hopp3 and K Zimmer1,4

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Laser-induced backside wet etching (LIBWE) is performed using ultrashort 248 nm laser pulses with a pulse duration of 600 fs to obtain sub-wavelength laser-induced periodic surface structures (LIPSS) on the back surface of fused silica which is in contact with a 0.5 mol l−1 solution of pyrene in toluene. The LIPSS are strictly one-dimensional patterns, oriented parallel to the polarization of the laser radiation, and have a constant period of about 140 nm at all applied laser fluences (0.33–0.84 J cm−2) and pulse numbers (50–1000 pulses). The LIPSS amplitude varies due to the inhomogeneous fluence in the laser spot. The LIPSS are examined with scanning electron microscopy (SEM) and atomic force microscopy (AFM). Their power spectral density (PSD) distribution is analysed at a measured area of 10 µm × 10 µm. The good agreement of the measured and calculated LIPSS periods strongly supports a mechanism based on the interference of surface-scattered and incident waves.


PACS

79.20.Ds Laser-beam impact phenomena

61.80.Ba Ultraviolet, visible, and infrared radiation effects (including laser radiation)

68.37.Ps Atomic force microscopy (AFM)

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.65.Cf Surface cleaning, etching, patterning

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 49 (10 December 2008)

Received 3 July 2008, in final form 2 October 2008

Published 18 November 2008



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