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Dynamic admittance of carbon nanotube-based molecular electronic devices and their equivalent electric circuit

ChiYung Yam1, Yan Mo1, Fan Wang1, Xiaobo Li1, GuanHua Chen1, Xiao Zheng1,2, Yuki Matsuda3, Jamil Tahir-Kheli3 and William A Goddard III3

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We use first-principles quantum mechanics to simulate the transient electrical response through carbon nanotube-based conductors under time-dependent bias voltages. The dynamic admittance and time-dependent charge distribution are reported and analyzed. We find that the electrical response of these two-terminal molecular devices can be mapped onto an equivalent classical electric circuit and that the switching time of these end-on carbon nanotube devices is only a few femtoseconds. This result is confirmed by studying the electric response of a simple two-site model device and is thus generalized to other two-terminal molecular electronic devices.


PACS

85.35.Kt Nanotube devices

85.65.+h Molecular electronic devices

84.30.Bv Circuit theory (including computer-aided circuit design and analysis)

Subjects

Electronics and devices

Nanoscale science and low-D systems

Dates

Issue 49 (10 December 2008)

Received 18 July 2008, in final form 15 October 2008

Published 18 November 2008



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