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Synthesis and field emission of single-crystalline copper vanadate nanobelts

Changjie Mao, Xiaojie Wang, Xingcai Wu1, Jun-Jie Zhu1 and Hong-Yuan Chen

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Single-crystalline nanobelts of a nonstoichiometric compound Cu1.55V2O6.55, with a thickness of 40–60 nm, width of 50–300 nm and length of several micrometers, have been synthesized on a large scale by a hydrothermal method. The structures and morphologies of the nanobelts were characterized by x-ray powder diffraction, x-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and high-resolution transmission electron microscopy. A probable growth mechanism has also been discussed. The nanobelts exhibit a turn-on field of 11.0 V µm−1, which is defined as the macroscopic field required to produce a current density of 10 µA cm−2. It is anticipated that the nanobelts can serve as a candidate material for future field emitters.


PACS

79.70.+q Field emission, ionization, evaporation, and desorption

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

61.46.-w Structure of nanoscale materials

61.05.cp X-ray diffraction

81.16.-c Methods of nanofabrication and processing

68.37.Lp Transmission electron microscopy (TEM)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 3 (23 January 2008)

Received 21 September 2007, in final form 7 November 2007

Published 11 December 2007



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